Copper(I)-Catalyzed Stereoselective Borylation Reactions

Copper(I)-Catalyzed Stereoselective Borylation Reactions
Author :
Publisher : Springer Nature
Total Pages : 236
Release :
ISBN-10 : 9789819910984
ISBN-13 : 9819910986
Rating : 4/5 (84 Downloads)

Book Synopsis Copper(I)-Catalyzed Stereoselective Borylation Reactions by : Yu Ozawa

Download or read book Copper(I)-Catalyzed Stereoselective Borylation Reactions written by Yu Ozawa and published by Springer Nature. This book was released on 2023-05-30 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book focuses on the development of novel functionalized organoboron compounds and those synthetic methods. High degrees of chemo-, regio-, and stereoselectivities of the borylation reactions are attained through catalyst design and optimization. Furthermore, the selectivity-determining mechanisms are analyzed with state-of-the-art DFT and other computational methods. In this book, the author synthesizes some multi-substituted alkenyl and allylic boronates via borylation reactions using a copper(I)/diboron catalyst system. Those compounds contain novel densely substituted and distorted structures, which have not been accessed by other methods. The high stereoselectivities are achieved by the optimization of the catalyst, especially the ligand. Some new ligands are also developed in this book. Furthermore, the derivatization of the borylation products is demonstrated to access the sterically demanding complex molecules. Also, the author performs computational analysis to reveal how the catalyst controls the selectivities. The deep insight into the reaction mechanism provides guides for rational catalyst design for not only copper(I) catalysis but also other transition metal catalysis. Thus, the content should be of interest to academic and industrial scientists in a wide range of areas.


Copper(I)-Catalyzed Stereoselective Borylation Reactions Related Books

Copper(I)-Catalyzed Stereoselective Borylation Reactions
Language: en
Pages: 236
Authors: Yu Ozawa
Categories: Science
Type: BOOK - Published: 2023-05-30 - Publisher: Springer Nature

DOWNLOAD EBOOK

This book focuses on the development of novel functionalized organoboron compounds and those synthetic methods. High degrees of chemo-, regio-, and stereoselect
Stereoselective Alkene Synthesis
Language: en
Pages: 283
Authors: Jianbo Wang
Categories: Science
Type: BOOK - Published: 2012-08-13 - Publisher: Springer

DOWNLOAD EBOOK

Stereoselective Synthesis of Tetrasubstituted Alkenes via Torquoselectivity-Controlled Olefination of Carbonyl Compounds with Ynolates, by Mitsuru Shindo and Ke
Computational Methods in Organometallic Catalysis
Language: en
Pages: 672
Authors: Yu Lan
Categories: Science
Type: BOOK - Published: 2021-03-24 - Publisher: John Wiley & Sons

DOWNLOAD EBOOK

The book includes a historical introduction to organometallic chemistry, a survey of mechanisms, and an extensive introduction to quantum mechanical computation
Organic Chemistry
Language: en
Pages: 1386
Authors: Pierre Vogel
Categories: Science
Type: BOOK - Published: 2019-10-07 - Publisher: John Wiley & Sons

DOWNLOAD EBOOK

Provides the background, tools, and models required to understand organic synthesis and plan chemical reactions more efficiently Knowledge of physical chemistry
Synthesis of Functionalized Organoboron Compounds Through Copper(I) Catalysis
Language: en
Pages: 222
Authors: Koji Kubota
Categories: Science
Type: BOOK - Published: 2017-06-27 - Publisher: Springer

DOWNLOAD EBOOK

This book describes state-of-the-art borylation chemistry using copper(I) catalysis. Enantioselective reactions are included to afford a variety of functionaliz